Product ID:ZINC-CLAD II ZINC RICH COATING ZINC DUST (S
MSDS Date:01/01/1991
FSC:8010
NIIN:00N037758
MSDS Number: BRDSM

SHERWIN-WILLIAMS CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

LBLG. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH

RTECS: 9999999ZZ

ARTICLES, FURNITURE/ANY INTERIOR SURF OF A

RTECS: 9999999ZZ

DO NOT APPLY ON ANY EXTERIOR SURF OF DWELLING UNITS,

RTECS: 9999999ZZ

WHICH CHILDREN MAY BE COMMONLY EXPOSED. PROD MAY BE

RTECS: 9999999ZZ

PKG, READ & FOLLOW WARNING LBL ON ALL COMPONENTS.

RTECS: 9999999ZZ

CAN BE HARMFUL/FATAL. BEFORE INITIAL USE OF

RTECS: 9999999ZZ

LEAD (29CFR1910.1025). USE ONLY W/ADEQ VENT. AVOID

RTECS: 9999999ZZ

COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE

RTECS: 9999999ZZ

SANDING/ABRADING OF DRIED FILM.

RTECS: 9999999ZZ

APPRVD PARTICULATE RESP FOR PROTECTION AGAINST

RTECS: 9999999ZZ

STD 1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

ZINC. PEL/TLV AS ZINC OXIDE

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 2%

OSHA PEL 10MG/M3 TDUST, 5FUME

ACGIH TLV: 10MG/M3 TDUST, 5FUME

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LEAD

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 0.12%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.15 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

0.1 MG/M3 FUME, 0.2 DUST

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: 0.04%

OSHA PEL SEE 1910.1027

ACGIH TLV: 0.01 MG/M3 DUST;9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

CAN OCCUR ONLY WHEN SAND/ABRADING DRY

RTECS: 9999999ZZ

PRLNGD OVEREXP TO SOLV INGRED MAY CAUSE ADVERSE EFTS

RTECS: 9999999ZZ

ASSOC RPTD & PRLNGD OVEREXP TO SOLV W/PERM BRAIN &

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& LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS TO

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LEAD CAS #

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SEEK CONSULTATION FROM APPROP PROFESSIONALS

RTECS: 9999999ZZ

CLSD CONTR. DISPOSE OF I/A/W FEDERAL,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. CERTAIN ZINC CLAD PROD CNTN LEAD. ACUTE OCCUP EXPOS TO
LEAD IS UNCOMMON, BUT RSLTS IN EFTS & SYMPS SIMILAR TO CHRONIC
OVEREXP. OVEREXP TO CADMIUM MAY RSLT IN KIDNEY DAM. CHRONIC:
CHRONIC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CADMIUM: ANTIC TO BE A CARCIN(NTP 6TH
ANN RPT), IARC GRP 2A(IARC MNGRPH VOL7, P139, 1987), OSHA REG.
Effects of Overexposure:HLTH HAZ:OVEREXP TO LEAD MAY RSLT IN DAM TO
BLOOD-FORMING, NERV, URIN & REPROD SYS (INCL EMBRYOTOX EFTS). SYMPS
INCL ABDOM DISCOMFORT/PAIN, CONSTIP, LOSS OF APPETITE, METALLIC
TASTE, NAUS, INSOMNIA, N ERV IRRITABILITY, WEAK, MUSCLE & JOINT
PAIN, HDCH & DIZZ. LONG TERM EXPOS TO HIGH LEVELS OF SILICA DUST,
WHICH (ING 4)
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN
SUSCEPTIBLE PERSONS OR SKIN SENSITIZATION.

First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH
WITH L ARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. INGEST: GET MEDICAL ATTENTION.

Lower Limits:0.7%
Upper Limits:6%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTRS(SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD.ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME.CLSD CONTRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT.APPLICATN TO HOT SURF(SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS, & OPEN
FLAME. DURING USE & UNTIL ALL VAPS ARE GONE; KEEP AREA VENTD-DO NOT
SMOKE. CONSULT NFPA CODE.
Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN
OFF STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF
IGNIT. USE APPRVD BOND & GROUND. KEEP CONTR CLSD WHEN NOT IN USE.
TRANSFER ONLY TO A PPRVD CONTRS W/COMPLETE & APPROP(ING 11)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIM BY VENT, WEAR A NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS. WHEN SAND,
WIREBRUSHING, ABRAD, BURN/WELD DRI ED FILM, WEAR A NIOSH/MSHA (ING
20)
Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS
IS MAINTAINED BELOW APPLIC EXPOS LIM. REFER TO OSHA (ING 21)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART #:PART F, B69D11.FIRE FIGHT PROC: TO PVNT PRESS
BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO
HAZ:REQS SPECIAL PREC.DURING EMER CNDTNS OVEREXP TO DECOMP PROD
MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED
ATTN. MATL TO AVOID:DANGEROUSLY INCR PRESS IN CSLD CNTR.

Boiling Pt:B.P. Text:>172F,>78C
Vapor Density:HVR/AIR
Spec Gravity:7.02
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:0-77

Stability Indicator/Materials to Avoid:YES
CONTAM OF ZINC-CNTNG PORTIONS/MIXT W/WATER, ACIDS/ALKALIS CAN CAUSE
EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METAL.

Waste Disposal Methods:WASTE FROM THESE PROD MAY BE HAZ AS DEFINED
UNDER RESOURCE CONSERVATION & RECOVERY ACT(RCRA) 40CFR261. WASTE
MUST BE TESTED FOR IGNITABILITY & EXTRACTABILITY TO DETERM APPLIC
EPA HAZ WASTE NUMBERS. IN CIN IN APPRVD FACILITY. DO NOT INCINERATE
(ING 10)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.